Question:

With excess bromine, phenol reacts to form

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Phenol reacts rapidly with Br\textsubscript{2} even in water, forming white precipitate of 2,4,6-tribromophenol.
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The Correct Option is C

Solution and Explanation

  • Phenol is highly reactive towards electrophilic aromatic substitution due to the activating effect of the -OH group.
  • In the presence of excess bromine, it undergoes tribromination at the ortho and para positions relative to the hydroxyl group.
  • Therefore, the major product is 2,4,6-tribromophenol.
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