Step 1: Analyze Statement I The rate law is:
\[ r = k[A]^2[B]. \]
When the concentrations of \(A\) and \(B\) are doubled:
\[ r' = k[2A]^2[2B] = k(2^2)[A]^2(2)[B]. \]
\[ r' = 8k[A]^2[B]. \]
Thus, \(r' = 8r\), so \(x = 8\).
Step 2: Analyze Statement II From the figure, the concentration decreases linearly with time. A linear decrease in concentration indicates a zero-order reaction (\(y = 0\)).
Final Step: Calculate \(x + y\)
\[ x + y = 8 + 0 = 8. \]
Final Answer: 8.
A(g) $ \rightarrow $ B(g) + C(g) is a first order reaction.
The reaction was started with reactant A only. Which of the following expression is correct for rate constant k ?
Rate law for a reaction between $A$ and $B$ is given by $\mathrm{R}=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}$. If concentration of A is doubled and concentration of B is halved from their initial value, the ratio of new rate of reaction to the initial rate of reaction $\left(\frac{\mathrm{r}_{2}}{\mathrm{r}_{1}}\right)$ is
For $\mathrm{A}_{2}+\mathrm{B}_{2} \rightleftharpoons 2 \mathrm{AB}$ $\mathrm{E}_{\mathrm{a}}$ for forward and backward reaction are 180 and $200 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively. If catalyst lowers $\mathrm{E}_{\mathrm{a}}$ for both reaction by $100 \mathrm{~kJ} \mathrm{~mol}^{-1}$. Which of the following statement is correct?
Match List-I with List-II: List-I