For hydrogen-like species, which of the following graphs provides the most appropriate representation of \( E \) vs \( Z \) plot for a constant \( n \)?
[E : Energy of the stationary state, Z : atomic number, n = principal quantum number]
Consider the following data:
- Heat of formation of \( CO_2(g) \) = -393.5 kJ mol\(^{-1}\)
- Heat of formation of \( H_2O(l) \) = -286.0 kJ mol\(^{-1}\)
- Heat of combustion of benzene = -3267.0 kJ mol\(^{-1}\)
The heat of formation of benzene is ……… kJ mol\(^{-1}\) (Nearest integer).
Which of the following is/are correct with respect to the energy of atomic orbitals of a hydrogen atom?
(A) \( 1s<2s<2p<3d<4s \)
(B) \( 1s<2s = 2p<3s = 3p \)
(C) \( 1s<2s<2p<3s<3p \)
(D) \( 1s<2s<4s<3d \)
Choose the correct answer from the options given below:
An ideal gas undergoes a cyclic transformation starting from point A and coming back to the same point by tracing the path A→B→C→D→A as shown in the three cases below.
Choose the correct option regarding \(\Delta U\):
Two circular discs of radius \(10\) cm each are joined at their centres by a rod, as shown in the figure. The length of the rod is \(30\) cm and its mass is \(600\) g. The mass of each disc is also \(600\) g. If the applied torque between the two discs is \(43\times10^{-7}\) dyne·cm, then the angular acceleration of the system about the given axis \(AB\) is ________ rad s\(^{-2}\).

Match the LIST-I with LIST-II for an isothermal process of an ideal gas system. 
Choose the correct answer from the options given below:
Which one of the following graphs accurately represents the plot of partial pressure of CS₂ vs its mole fraction in a mixture of acetone and CS₂ at constant temperature?
