Question:

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : The ionic radii of \(O^{2–}\) and \(Mg^{2+}\) are same.
Reason (R) : Both \(O^{2–}\) and \(Mg^{2+}\) are isoelectronic species.
In the light of the above statements, choose the correct answer from the options given below.

Updated On: Sep 24, 2024
  • Both (A) and (R) are true and (R) is the correct explanation of (A).
  • Both (A) and (R) are true but (R) is not the correct explanation of (A).
  • (A) is true but (R) is false.
  • (A) is false but (R) is true.
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The Correct Option is D

Solution and Explanation

Correct order of ionic radii:

\(O^{–2} > Mg^{+2}\)

This is because among isoelectronic species, the size of anions are greater than the size of cations.

Statement (II) is correct as both \(O^{–2}\) and \(Mg^{+2}\) are isoelectronic.

Hence, the correct option is (D): (A) is false but (R) is true.

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