In an isothermal process, the temperature (\( T \)) remains constant: \[ dT = 0 \]
The internal energy (\( U \)) of an ideal gas depends only on temperature. Since \( dT = 0 \), we have: \[ dU = 0 \] Thus, the internal energy remains constant.
From the First Law of Thermodynamics: \[ dQ = dU + dW \] Since \( dU = 0 \), this reduces to: \[ dQ = dW \] Therefore, the heat absorbed (\( dQ \)) is entirely used for work done (\( dW \)).
- If \( dQ > 0 \) (heat is absorbed by the system), then \( dW > 0 \) (work is done by the system).
- This implies both heat transfer and work done are positive in an isothermal process.
The correct answer is (C): (c), (e).
Consider that specific heat (0 to \(50~^\circ\mathrm{C}\)) of water, water vapour and air remains constant: \(4.48\), \(1.88\) and \(1.0~\mathrm{kJ/(kg\^\circ C)}\), respectively. Assuming the heat energy required to convert \(1~\mathrm{kg}\) of water to water vapour at \(0~^\circ\mathrm{C}\) is \(2000~\mathrm{kJ}\), the enthalpy (in kJ/kg dry air) of atmospheric air containing \(0.05~\mathrm{kg}\) water vapour per kg dry air at \(50~^\circ\mathrm{C}\) is ________. (rounded off to 1 decimal place)
In hot weather, a human body cools by evaporation of sweat. The amount of water that must evaporate to cool the body by \(1~^\circ\mathrm{C}\) is __________________________% of the body mass. (Round off to two decimal places)
[Given: latent heat of vaporization of water \(L_v=2.25\times10^6~\mathrm{J\,kg^{-1}}\); specific heat capacities of body and water \(c=4.2\times10^3~\mathrm{J\,kg^{-1}\,K^{-1}}\).]
One kg of dry air at \(15~^\circ\mathrm{C}\) is isothermally compressed to one–tenth of its initial volume. The work done on the system is ______________________________________ kJ. (Round off to the nearest integer) [Use the gas constant for dry air \(R=287~\mathrm{J\,kg^{-1}\,K^{-1}}\).]
Electrolysis of 600 mL aqueous solution of NaCl for 5 min changes the pH of the solution to 12. The current in Amperes used for the given electrolysis is ….. (Nearest integer).
Thermodynamics in physics is a branch that deals with heat, work and temperature, and their relation to energy, radiation and physical properties of matter.
The first law of thermodynamics, also known as the Law of Conservation of Energy, states that energy can neither be created nor destroyed; energy can only be transferred or changed from one form to another.
The second law of thermodynamics says that the entropy of any isolated system always increases. Isolated systems spontaneously evolve towards thermal equilibrium—the state of maximum entropy of the system. More simply put: the entropy of the universe (the ultimate isolated system) only increases and never decreases.
The third law of thermodynamics states that the entropy of a system approaches a constant value as the temperature approaches absolute zero. The entropy of a system at absolute zero is typically zero, and in all cases is determined only by the number of different ground states it has. Specifically, the entropy of a pure crystalline substance (perfect order) at absolute zero temperature is zero