We are given two linear equations:
1. \( 2x + ky = 1 \)
2. \( 3x - 5y = 7 \)
For the system of linear equations to have a unique solution, the determinant of the coefficients must be non-zero. The determinant \( D \) of the coefficient matrix is given by:
\[
D = \begin{vmatrix} 2 & k \\ 3 & -5 \end{vmatrix}.
\]
The determinant is calculated as:
\[
D = (2)(-5) - (3)(k) = -10 - 3k.
\]
For the system to have a unique solution, \( D \neq 0 \). Therefore, we require:
\[
-10 - 3k \neq 0.
\]
Solving for \( k \):
\[
-3k \neq 10 \quad \implies \quad k \neq -\frac{10}{3}.
\]
Conclusion:
The system will have a unique solution if \( k \neq -\frac{10}{3} \).