Standard entropies of \(X_2\), \(Y_2\) and \(XY_5\) are 70, 50, and 110 J \(K^{-1}\) mol\(^{-1}\) respectively. The temperature in Kelvin at which the reaction \[ \frac{1}{2} X_2 + \frac{5}{2} Y_2 \rightarrow XY_5 \quad \Delta H = -35 \, {kJ mol}^{-1} \] will be at equilibrium is (nearest integer):
In the following substitution reaction: 
The correct increasing order of stability of the complexes based on \( \Delta \) value is:
Two light beams fall on a transparent material block at point 1 and 2 with angle \( \theta_1 \) and \( \theta_2 \), respectively, as shown in the figure. After refraction, the beams intersect at point 3 which is exactly on the interface at the other end of the block. Given: the distance between 1 and 2, \( d = 4/3 \) cm and \( \theta_1 = \theta_2 = \cos^{-1} \frac{n_2}{2n_1} \), where \( n_2 \) is the refractive index of the block and \( n_1 \) is the refractive index of the outside medium, then the thickness of the block is cm. 