Fe3+ cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solution due to the formation of:
- [Fe(H2O)6]2 [Fe(CN)6]
- Fe2[Fe(CN)6]2
- Fe3[Fe(OH)2 (CN)4]2
- Fe4[Fe(CN)6]3
The Correct Option is D
Solution and Explanation
Top Questions on coordination compounds
Given below are two statements regarding conformations of n-butane. Choose the correct option.
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- The correct statement among the following is:
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Consider a weak base \(B\) of \(pK_b = 5.699\). \(x\) mL of \(0.02\) M HCl and \(y\) mL of \(0.02\) M weak base \(B\) are mixed to make \(100\) mL of a buffer of pH \(=9\) at \(25^\circ\text{C}\). The values of \(x\) and \(y\) respectively are
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- \(20.0\,\text{dm}^3\) of an ideal gas \(X\) at \(600\) K and \(0.5\) MPa undergoes isothermal reversible expansion until the pressure of the gas becomes \(0.2\) MPa. Which of the following option is correct? (Given: \(\log 2 = 0.3010\), \(\log 5 = 0.6989\))
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- From the following : (A) $[\text{Co}(\text{NH}_3)_6]^{3+}$ : Inner orbital complex, $d^2sp^3$ hybridization (B) $[\text{MnCl}_4]^{2-}$ : Outer orbital complex, $sp^3d^2$ hybridization (C) $[\text{CoF}_6]^{3-}$ : Outer orbital complex, $d^2sp^3$ hybridization (D) $[\text{FeF}_6]^{3-}$ : Outer orbital complex, $sp^3d^2$ hybridization (E) $[\text{Ni}(\text{CN})_4]^{2-}$ : Inner orbital complex, $sp^3$ hybridization Choose the correct answer from the given options.
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Questions Asked in JEE Main exam
Two circular discs of radius \(10\) cm each are joined at their centres by a rod, as shown in the figure. The length of the rod is \(30\) cm and its mass is \(600\) g. The mass of each disc is also \(600\) g. If the applied torque between the two discs is \(43\times10^{-7}\) dyne·cm, then the angular acceleration of the system about the given axis \(AB\) is ________ rad s\(^{-2}\).
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Match the LIST-I with LIST-II for an isothermal process of an ideal gas system.
Choose the correct answer from the options given below:
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- A bag contains 10 balls out of which \( k \) are red and \( (10-k) \) are black, where \( 0 \le k \le 10 \). If three balls are drawn at random without replacement and all of them are found to be black, then the probability that the bag contains 1 red and 9 black balls is:
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Which one of the following graphs accurately represents the plot of partial pressure of CS₂ vs its mole fraction in a mixture of acetone and CS₂ at constant temperature?
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Concepts Used:
Werner’s Theory of Coordination Compounds
In 1893 Werner produced a theory to explain the structures, formation and nature of bonding in the coordination compounds. This theory is known as Werner’s theory of coordination compounds.
Postulates of Werner's Theory:
The important postulates as observed by Alfred Werner throughout his experiments are as follows:
- The complex/ coordination compounds contain a central metal atom.
- The metal atoms in a coordination compound generally show two types of valency: primary valency and secondary valency.
- The primary valencies denote the oxidation state. They are ionizable and are satisfied by the negative ions.
- Secondary valencies denote the coordination number. They are non-ionizable and are fixed for every metal atom. The secondary valency is generally satisfied by the neutral molecules or negative ions.
- The metal atoms should satisfy both primary and secondary valencies.
- The secondary valency of the atom basically shows the geometry/ polyhedra of the particular coordination compound.
Limitations of Werner’s Theory:
- Though Werner explained some properties of the coordination compound, he failed to explain the colour of the coordinate compound.
- He could not explain the magnetic and optical properties of coordination compounds.
- He could not answer the question, why does the coordination sphere have a definite geometry.