Lanthanide Contraction: A gradual decrease in atomic and ionic radii across the lanthanide series due to poor shielding by 4f electrons.
Reason for Colour: Transition elements have partially filled d-orbitals. When light falls on them, d-d transitions occur, absorbing certain wavelengths and reflecting others, giving them color.
(i) Ethanol is heated with sodium bromide and conc. \( H_2SO_4 \):
(ii) Toluene reacts with \( Cl_2 \) gas in the presence of Fe powder in the dark:
(iii) Benzene diazonium chloride reacts with water:
(iv) 2-Bromopentane is heated with alcoholic \( KOH \):