Excess of $PCl_5$ reacts with conc. $H_2SO_4$ giving
- chlorosulphonic acid
- thionyl chloride
- sulphuryl chloride
- sulphurous acid
The Correct Option is C
Solution and Explanation
$\underset{\text{sulphuric acid }}{SO _{2}( OH )_{2}}+2 PCl _{5} \longrightarrow \underset{\text{sulphuryl chloride }}{SO _{2} Cl _{2}} +2 POCl _{3}+2 HCl$
Top Questions on p -Block Elements
Given below are two statements.
In the light of the above statements, choose the correct answer from the options given below:- JEE Main - 2025
- Chemistry
- p -Block Elements
Given below are two statements:
Statement I: Nitrogen forms oxides with +1 to +5 oxidation states due to the formation of $\mathrm{p} \pi-\mathrm{p} \pi$ bond with oxygen.
Statement II: Nitrogen does not form halides with +5 oxidation state due to the absence of d-orbital in it.
In the light of the above statements, choose the correct answer from the options given below:- JEE Main - 2025
- Chemistry
- p -Block Elements
Given below are the pairs of group 13 elements showing their relation in terms of atomic radius. $(\mathrm{B}<\mathrm{Al}),(\mathrm{Al}<\mathrm{Ga}),(\mathrm{Ga}<\mathrm{In})$ and $(\mathrm{In}<\mathrm{Tl})$ Identify the elements present in the incorrect pair and in that pair find out the element (X) that has higher ionic radius $\left(\mathrm{M}^{3+}\right)$ than the other one. The atomic number of the element (X) is
- JEE Main - 2025
- Chemistry
- p -Block Elements
- In which of the following species, the ratio of s-electrons to p-electrons is the same?
- TS EAMCET - 2024
- Chemistry
- p -Block Elements
- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below:- JEE Main - 2024
- Chemistry
- p -Block Elements
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A block of certain mass is placed on a rough floor. The coefficients of static and kinetic friction between the block and the floor are 0.4 and 0.25 respectively. A constant horizontal force \( F = 20 \, \text{N} \) acts on it so that the velocity of the block varies with time according to the following graph. The mass of the block is nearly (Take \( g = 10 \, \text{m/s}^2 \)):
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- A random experiment has five outcomes \(w_1, w_2, w_3, w_4, w_5\). The probabilities of the occurrence of the outcomes \(w_1, w_2, w_4, w_5\) are respectively \( \frac{1}{6}, a, b, \frac{1}{12} \) such that \(12a + 12b - 1 = 0\). Then the probabilities of occurrence of the outcome \(w_3\) is:
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A wooden block of mass M lies on a rough floor. Another wooden block of the same mass is hanging from the point O through strings as shown in the figure. To achieve equilibrium, the coefficient of static friction between the block on the floor and the floor itself is
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Concepts Used:
P-Block Elements
- P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
- P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.
P block elements consist of:
- Group 13 Elements: Boron family
- Group 14 Elements: Carbon family
- Group 15 Elements: Nitrogen family
- Group 16 Elements: Oxygen family
- Group 17 Elements: Fluorine family
- Group 18 Elements: Neon family