Question:

Consider the following reactions: \[ \text{Cs} + O_2 (\text{excess}) \rightarrow X \] \[ \text{Cs} + O_2 (\text{limited}) \rightarrow X \] \[ \text{Na} + O_2 \rightarrow Y \] Identify the correct statement about \( X \) and \( Y \).

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Alkali metal oxides vary by size:
- Li forms normal oxides (\( O^{2-} \)).
- Na forms peroxides (\( O_2^{2-} \)).
- K, Rb, and Cs form superoxides (\( O_2^{-} \)).
Updated On: Mar 11, 2025
  • \( Y \) is monoxide and \( X \) is superoxide
  • \( Y \) is peroxide and \( X \) is peroxide
  • \( Y \) is peroxide and \( X \) is superoxide
  • \( Y \) is superoxide and \( X \) is peroxide
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The Correct Option is C

Solution and Explanation

Step 1: Understanding Alkali Metal Oxides Formation
Alkali metals react with oxygen in different oxidation states, forming:
- Normal oxides (\(O^{2-}\)): Found in small alkali metals like Li.
- Peroxides (\(O_2^{2-}\)): Formed by Na, K.
- Superoxides (\(O_2^{-}\)): Formed by larger alkali metals like K, Rb, and Cs.
Step 2: Identifying \( X \) (Cs with O\(_2\))
- Cesium (\( Cs \)) reacts with excess oxygen to form superoxide (\( CsO_2 \)).
- Superoxides contain \( O_2^- \) and are found in larger alkali metals (K, Rb, Cs).
- Hence, \( X \) is a superoxide (\( CsO_2 \)).
Step 3: Identifying \( Y \) (Na with O\(_2\))
- Sodium (\( Na \)) reacts with oxygen to form peroxide (\( Na_2O_2 \)).
- Sodium does not form superoxides under normal conditions.
- Hence, \( Y \) is a peroxide (\( Na_2O_2 \)).
Step 4: Matching the Correct Option
- \( Y \) is peroxide (\( Na_2O_2 \)).
- \( X \) is superoxide (\( CsO_2 \)).
- The correct statement is option (3): \( Y \) is peroxide and \( X \) is superoxide.
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