Consider the following metal complexes:
[Co(NH3)6]3+
[CoCl(NH3)5]2+
[Co(CN)6]3–
[Co(NH3)5(H2O)]3+
The spin-only magnetic moment value of the complex that absorbs light with shortest wavelength is _______ B.M. (Nearest integer)
Consider the following metal complexes:
[Co(NH3)6]3+
[CoCl(NH3)5]2+
[Co(CN)6]3–
[Co(NH3)5(H2O)]3+
The spin-only magnetic moment value of the complex that absorbs light with shortest wavelength is _______ B.M. (Nearest integer)
Correct Answer: 0
Solution and Explanation
In all complexes, Co is present in the +3 oxidation state and all complexes are low spin or inner orbital complex.
The stronger the ligand, the higher the crystal field splitting.
So, the order of crystal field splitting is
[Co(CN)6]3– > [Co(NH3)6]3+> [Co(NH3)5(H2O)]3+ > [CoCl(NH3)5]2+.
The shortest wavelength is shown by the complex having maximum crystal field splitting.
spin magnetic moment=\(\sqrt{0(0+2)}\)=0 BM
Top Questions on coordination compounds
- (ii) Carry out the following conversions: (I) Benzaldehyde to Benzophenone
- CBSE CLASS XII - 2025
- Chemistry
- coordination compounds
- PCl$_3$, 2KCl does not give precipitate of AgCl with AgNO$_3$ solution. Write the structural formula and IUPAC name of the complex.
- CBSE CLASS XII - 2025
- Chemistry
- coordination compounds
- The coordination number and oxidation number of \(\mathrm{Cr}\) in \(\mathrm{K}\left[\mathrm{Cr}\left(\mathrm{H}_2\mathrm{O}\right)_2\left(\mathrm{C}_2\mathrm{O}_4\right)_2\right]\) are:
- UPCATET - 2025
- Chemistry
- coordination compounds
- Optical isomerism is shown by:
- UPCATET - 2025
- Chemistry
- coordination compounds
- Hybridisation of \(\mathrm{Ni}\) in \(\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-\) is:}
- UPCATET - 2025
- Chemistry
- coordination compounds
Questions Asked in JEE Main exam
- Let \( [x] \) denote the greatest integer function, and let \( m \) and \( n \) respectively be the numbers of the points, where the function \( f(x) = [x] + |x - 2| \), \( -2<x<3 \), is not continuous and not differentiable. Then \( m + n \) is equal to:
- JEE Main - 2025
- Differential Equations
- Let \( f(x) = \frac{x - 5}{x^2 - 3x + 2} \). If the range of \( f(x) \) is \( (-\infty, \alpha) \cup (\beta, \infty) \), then \( \alpha^2 + \beta^2 \) equals to.
- JEE Main - 2025
- Functions
- Let \( P_n = \alpha^n + \beta^n \), \( P_{10} = 123 \), \( P_9 = 76 \), \( P_8 = 47 \), and \( P_1 = 1 \). The quadratic equation whose roots are \( \frac{1}{\alpha} \) and \( \frac{1}{\beta} \) is:
- JEE Main - 2025
- Sequences and Series
- The value of \( (\sin 70^\circ)(\cot 10^\circ \cot 70^\circ - 1) \) is:
- JEE Main - 2025
- Trigonometric Identities
Let $ P_n = \alpha^n + \beta^n $, $ n \in \mathbb{N} $. If $ P_{10} = 123,\ P_9 = 76,\ P_8 = 47 $ and $ P_1 = 1 $, then the quadratic equation having roots $ \alpha $ and $ \frac{1}{\beta} $ is:
- JEE Main - 2025
- Relations and functions
Concepts Used:
Coordination Compounds
A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.
Coordination entity:
A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.
Ligands:
A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.