\((i)\begin{bmatrix}a&b\\-b&a\end{bmatrix}+\begin{bmatrix}a&b\\b&a\end{bmatrix}\)\(=\begin{bmatrix}a+a& b+b\\ -b+b& a+a\end{bmatrix}\)\(=\begin{bmatrix}2a& 2b\\ 0& 2a\end{bmatrix}\)
\((ii)\begin{bmatrix}a^2+b^2& b^2+c^2\\ a^2+c^2& a^2+b^2\end{bmatrix}+\begin{bmatrix}2ab& 2bc \\-2ac& -2ab\end{bmatrix}\)
\(=\begin{bmatrix}a^2+b^2+2ab& b^2+c^2+2bc\\ a^2+c^2-2ac& a^2+b^2-2ab\end{bmatrix}\)
\(=\begin{bmatrix}(a+b)^2& (b+c)^2\\ (a-c)^2& (a-b)^2\end{bmatrix}\)
\((iii)\begin{bmatrix}-1&4&-6\\ 8&5&16\\ 2&8&5\end{bmatrix}+\begin{bmatrix}12&7&6 \\8&0&5\\ 3&2&4\end{bmatrix}\)
\(=\begin{bmatrix}-1+12& 4+7& -6+6\\ 8+8& 5+0& 16+5\\ 2+3& 8+2& 5+4\end{bmatrix}\)
\(=\begin{bmatrix}11& 11& 0\\ 16& 5& 21\\ 5& 10& 9\end{bmatrix}\)
\((iv)\begin{bmatrix}cos^2x& sin^2x\\ sin^2x& cos^2x\end{bmatrix}+\begin{bmatrix}sin^2x& cos^2x\\ cos^2x& sin2x\end{bmatrix}\)
\(=\begin{bmatrix}cos^2x+sin^2x& sin^2x+cos^2x\\ sin^2x+cos^2x& cos^2x+sin^2x\end{bmatrix}\)
\(=\begin{bmatrix}1& 1\\ 1& 1\end{bmatrix}\)\((\because sin^2x+cos^2x=1)\)
If matrix \[ A = \begin{bmatrix} 1 & 1 & 3 \\ 1 & 3 & -3 \\ -2 & -4 & -4 \end{bmatrix}, \] then find \( A^{-1} \).
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.