Question:

An ideal gas is contained in a cylinder with a movable piston. The gas undergoes an isothermal expansion from a volume of 2 liters to 8 liters at a temperature of 300 K. If the initial pressure of the gas is \( 2 \times 10^5 \, \text{Pa} \), calculate the work done by the gas during this expansion. (Use \( R = 8.31 \, \text{J/mol·K} \))

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For isothermal processes, the work done by the gas can be calculated using the equation \( W = nRT \ln \left( \frac{V_f}{V_i} \right) \). Always remember to convert units where necessary (e.g., liters to cubic meters).
Updated On: Apr 15, 2025
  • \( 7200 \, \text{J} \)
  • \( 3600 \, \text{J} \)
  • \( 1800 \, \text{J} \)
  • \( 14400 \, \text{J} \)
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The Correct Option is A

Solution and Explanation

For an isothermal expansion of an ideal gas, the work done by the gas is given by: \[ W = nRT \ln \left( \frac{V_f}{V_i} \right) \] Where: - \( W \) is the work done by the gas, - \( n \) is the number of moles of the gas, - \( R = 8.31 \, \text{J/mol·K} \) is the universal gas constant, - \( T = 300 \, \text{K} \) is the temperature, - \( V_f = 8 \, \text{L} \) is the final volume, - \( V_i = 2 \, \text{L} \) is the initial volume. First, we calculate the number of moles \( n \) of the gas using the ideal gas equation: \[ PV = nRT \] Substitute the given values: \[ (2 \times 10^5) \times (2 \times 10^{-3}) = n \times 8.31 \times 300 \] \[ n = \frac{(2 \times 10^5) \times (2 \times 10^{-3})}{8.31 \times 300} \approx 0.16 \, \text{mol} \] Now, calculate the work done: \[ W = 0.16 \times 8.31 \times 300 \times \ln \left( \frac{8}{2} \right) \] \[ W = 0.16 \times 8.31 \times 300 \times \ln(4) \] \[ W \approx 7200 \, \text{J} \] Thus, the work done by the gas is \( 7200 \, \text{J} \).
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