Step 1: Calculate the efficiencies of each engine. The efficiency \(\eta\) of a Carnot engine is given by: \[ \eta = 1 - \frac{T_{\text{cold}}} {T_{\text{hot}}} \] For \(E_1\): \[ \eta_1 = 1 - \frac{373}{473} \] For \(E_2\): \[ \eta_2 = 1 - \frac{273}{373} \]
Step 2: Calculate the overall efficiency of two engines working in series. The overall efficiency \(\eta_{12}\) when two Carnot engines operate in series is the product of their individual efficiencies, not the sum: \[ \eta_{12} = \eta_1 \times \eta_2 = \left(1 - \frac{373}{473}\right) \times \left(1 - \frac{273}{373}\right) \] This can be simplified and calculated for the exact values.
Step 3: Verify the relationship. \[ \eta_{12} = \left(1 - \frac{373}{473}\right) \times \left(1 - \frac{273}{373}\right) \] \[ \eta_{12} = \left(\frac{100}{473}\right) \times \left(\frac{100}{373}\right) \] \[ \eta_{12} \approx \left(\frac{100}{473}\right) \times \left(\frac{100}{373}\right) \approx 0.0567 \] Which indicates the multiplicative relationship is correct as per the properties of series Carnot engines.
The steam volatile compounds among the following are: