Question:

An element crystallising in body centred cubic lattice has an edge length of $500\,pm$. If its density is $4\,g\,cm^{-3}$, the atomic mass of the element (in $g \,mol^{-1}$) is (consider $N_A = 6 \times 10^{23}$)

Updated On: Jun 6, 2022
  • $100$
  • $250$
  • $125$
  • $150$
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The Correct Option is D

Solution and Explanation

Relation used,

Density $(\rho) =\frac{Z \times M}{a^{3} \times N_{A}}$

where, $Z =$ contribution factor

$M =$ molar mass of particle

$a =$ edge length

$\rho =$ density of crystal

Given, $N_{A} =$ Avogadro's number

$=6 \times 10^{23}$
$\rho =4 g / cm ^{3}$
$Z =2$ (crystal has bcc structure)

$\therefore M=\frac{\rho \times a^{3} \times N_{A}}{Z}$
$=\frac{4 \times\left(500 \times 10^{-10}\right)^{3} \times 6 \times 10^{23}}{2}$
$M =\frac{4 \times(5)^{3} \times 6 \times 10^{-1}}{2}$
$=\frac{4 \times 125 \times 6 \times 10^{-1}}{2}$
$M =\frac{300}{2}=150\, g\, mol ^{-1}$
$\therefore$ The atomic mass of the element (in $g\, mol ^{-1}$ ) is 150 .
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Concepts Used:

Solid State

Solids are substances that are featured by a definite shape, volume, and high density. In the solid-state, the composed particles are arranged in several manners. Solid-state, in simple terms, means "no moving parts." Thus solid-state electronic devices are the ones inclusive of solid components that don’t change their position. Solid is a state of matter where the composed particles are arranged close to each other. The composed particles can be either atoms, molecules, or ions. 

Solid State

Types of Solids:

Based on the nature of the order that is present in the arrangement of their constituent particles solids can be divided into two types;

  • Amorphous solids behave the same as super cool liquids due to the arrangement of constituent particles in short-range order. They are isotropic and have a broad melting point (range is about greater than 5°C).
  • Crystalline solids have a fixed shape and the constituent particles are arranged in a long-range order.