Amines are usually formed from amides, imides, halides, nitro compounds, etc. They exhibit hydrogen bonding which influences their physical properties. In alkyl amines, a combination of electron releasing, steric and H-bonding factors influence the stability of the substituted ammonium cations in protic polar solvents and thus affect the basic nature of amines. Alkyl amines are found to be stronger bases than ammonia. Amines being basic in nature, react with acids to form salts. Aryldiazonium salts, undergo replacement of the diazonium group with a variety of nucleophiles to produce aryl halides, cyanides, phenols and arenes.
Arrange the following in increasing order of their basic strength in aqueous solution:
CH$_3$–NH$_2$, (CH$_3$)$_2$NH, (CH$_3$)$_3$N
Amines are usually formed from amides, imides, halides, nitro compounds, etc. They exhibit hydrogen bonding which influences their physical properties. In alkyl amines, a combination of electron releasing, steric and H-bonding factors influence the stability of the substituted ammonium cations in protic polar solvents and thus affect the basic nature of amines. Alkyl amines are found to be stronger bases than ammonia. Amines being basic in nature, react with acids to form salts. Aryldiazonium salts, undergo replacement of the diazonium group with a variety of nucleophiles to produce aryl halides, cyanides, phenols and arenes.
Arrange the following in increasing order of their basic strength in aqueous solution:
CH$_3$–NH$_2$, (CH$_3$)$_2$NH, (CH$_3$)$_3$N
Show Hint
Solution and Explanation
(CH$_3$)$_3$N>(CH$_3$)$_2$NH>CH$_3$–NH$_2$
Top Questions on Amines
Which of the following amines does not give foul smell of isocyanide on heating with chloroform and ethanolic KOH ?
- Anilinium hydrogen sulphate on heating at 453–473 K produces which of the following as a major product ?
- How can you convert propanenitrile to 1-aminopropane?
- An amine ‘X’ reacts with Hinsberg reagent and the product obtained is insoluble in alkali. The amine ‘X’ is:
Amines are usually formed from amides, imides, halides, nitro compounds, etc. They exhibit hydrogen bonding which influences their physical properties. In alkyl amines, a combination of electron releasing, steric and H-bonding factors influence the stability of the substituted ammonium cations in protic polar solvents and thus affect the basic nature of amines. Alkyl amines are found to be stronger bases than ammonia. Amines being basic in nature, react with acids to form salts. Aryldiazonium salts, undergo replacement of the diazonium group with a variety of nucleophiles to produce aryl halides, cyanides, phenols and arenes.
How can you convert the following:
(i) Ethanoic acid to methanamine
Questions Asked in CBSE CLASS XII exam
- Find the image \( A' \) of the point \( A(2,1,2) \) in the line \[ l: \mathbf{r} = 4\hat{i} + 2\hat{j} + 2\hat{k} + \lambda (\hat{i} - \hat{j} - \hat{k}). \] Also, find the equation of the line joining \( A A' \). Find the foot of the perpendicular from point \( A \) on the line \( l \).
- If a line makes angles of \( \frac{3\pi}{4} \) and \( \frac{\pi}{3} \) with the positive directions of \( x \), \( y \), and \( z \)-axes respectively, then \( \theta \) is:
- Differentiate \(\frac{\sin x}{\sqrt{\cos x}}\) with respect to x.
- CBSE CLASS XII - 2025
- Differentiation
- For a reaction X + Y → Z, in which both X and Y follow first order kinetics; if the concentration of X is increased 2 times and concentration of Y is increased 3 times, how does it affect the rate of reaction?
- CBSE CLASS XII - 2025
- Chemical Kinetics
- Find the angle at which the given lines are inclined to each other: \[ l_1: \frac{x - 5}{2} = \frac{y + 3}{1} = \frac{z - 1}{-3} \] \[ l_2: \frac{x}{3} = \frac{y - 1}{2} = \frac{z + 5}{-1} \]