A source of sound emits sound waves at frequency \( f_0 \). It is moving towards an observer with fixed speed \( v_s \) (\( v_s < v \), where \( v \) is the speed of sound in air). If the observers were to move towards the source with speed \( v_0 \), one of the following two graphs (A and B) will give the correct variation of the frequency \( f \) heard by the observer as \( v_0 \) changes.

200 ml of an aqueous solution contains 3.6 g of Glucose and 1.2 g of Urea maintained at a temperature equal to 27$^{\circ}$C. What is the Osmotic pressure of the solution in atmosphere units?
Given Data R = 0.082 L atm K$^{-1}$ mol$^{-1}$
Molecular Formula: Glucose = C$_6$H$_{12}$O$_6$, Urea = NH$_2$CONH$_2$