For an adiabatic process, the work done \( W \) is given by:
\[ W = \frac{nR\Delta T}{1-\gamma}. \]
1. **Using the Adiabatic Condition:**
Since the process is adiabatic, \( TV^{\gamma-1} = \text{constant} \). Let the initial temperature be \( T \) and the final temperature be \( T_f \) when the volume is doubled. Thus,
\[ TV^{\gamma-1} = T_f(2V)^{\gamma-1}. \]
2. **Calculate \( T_f \):**
Simplifying, we get:
\[ T_f = T \left(\frac{1}{2}\right)^{\frac{\gamma-1}{\gamma}} = T \left(\frac{1}{2}\right)^{\frac{1}{2}} = \frac{T}{\sqrt{2}}. \]
3. **Calculate the Work Done:**
Substitute into the work formula:
\[ W = \frac{R(T - T_f)}{1 - \frac{3}{2}} = \frac{R \left( T - \frac{T}{\sqrt{2}} \right)}{-\frac{1}{2}}. \] Simplifying further:
\[ W = 2RT\frac{\left(\sqrt{2} - 1\right)}{\sqrt{2}} = RT(2 - \sqrt{2}). \] **Answer:** \( RT(2 - \sqrt{2}) \)
For a given reaction \( R \rightarrow P \), \( t_{1/2} \) is related to \([A_0]\) as given in the table. Given: \( \log 2 = 0.30 \). Which of the following is true?
\([A]\) (mol/L) | \(t_{1/2}\) (min) |
---|---|
0.100 | 200 |
0.025 | 100 |
A. The order of the reaction is \( \frac{1}{2} \).
B. If \( [A_0] \) is 1 M, then \( t_{1/2} \) is \( 200/\sqrt{10} \) min.
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. \( t_{1/2} \) is 800 min for \( [A_0] = 1.6 \) M.
Two vessels A and B are connected via stopcock. Vessel A is filled with a gas at a certain pressure. The entire assembly is immersed in water and allowed to come to thermal equilibrium with water. After opening the stopcock the gas from vessel A expands into vessel B and no change in temperature is observed in the thermometer. Which of the following statement is true?
Choose the correct nuclear process from the below options:
\( [ p : \text{proton}, n : \text{neutron}, e^- : \text{electron}, e^+ : \text{positron}, \nu : \text{neutrino}, \bar{\nu} : \text{antineutrino} ] \)
Let \( T_r \) be the \( r^{\text{th}} \) term of an A.P. If for some \( m \), \( T_m = \dfrac{1}{25} \), \( T_{25} = \dfrac{1}{20} \), and \( \displaystyle\sum_{r=1}^{25} T_r = 13 \), then \( 5m \displaystyle\sum_{r=m}^{2m} T_r \) is equal to: