Question:

A human body required the 0.01 M activity of radioactive substance after 24 h. Half-life of radioactive substance is 6 h. Then, injection of maximum activity of radioactive substance that can be injected will be

Updated On: Jul 15, 2024
  • 0.08
  • 0.04
  • 0.16
  • 0.32
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The Correct Option is C

Approach Solution - 1

Remaining activity = 0.01 M after 24 h
Remaining activity
$\, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, \, $=Initial activity $\times\Bigg(\frac{1}{2}\Bigg)^n$
Used half-life time(n)=$\frac{Total time}{t_{1/2}}=\frac{24}{6}=4$
So $\, \, \, \, \, \, \, $0.01 = Initial activity $\times\Bigg(\frac{1}{2}\Bigg)^4$
Initial activity = 0.01 $\times$ 16 = 0.16
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Approach Solution -2

To determine the maximum activity of the radioactive substance that can be injected into the human body to achieve an activity of 0.01 M after 24 hours, we need to use the concept of radioactive decay and the half-life formula.
Given:
- Required activity after 24 hours: \( A_{24} = 0.01 \) M
- Half-life of the radioactive substance: \( t_{1/2} = 6 \) hours
 Formula for Radioactive Decay:
The activity of a radioactive substance after a certain time period can be calculated using the formula:
\[A_t = A_0 \left(\frac{1}{2}\right)^{\frac{t}{t_{1/2}}}\]
where:
- \( A_t \) is the activity after time \( t \)
- \( A_0 \) is the initial activity
- \( t \) is the time elapsed
- \( t_{1/2} \) is the half-life of the substance
Steps to Determine the Maximum Initial Activity (\( A_0 \)):
1. Determine the decay factor:
  \[\left(\frac{1}{2}\right)^{\frac{t}{t_{1/2}}} = \left(\frac{1}{2}\right)^{\frac{24}{6}} = \left(\frac{1}{2}\right)^4 = \frac{1}{16}\]
2. Use the decay formula to find \( A_0 \):
  \[  A_{24} = A_0 \left(\frac{1}{16}\right)  \]
  \[  0.01 = A_0 \times \frac{1}{16}  \]
3. Solve for \( A_0 \):
  \[A_0 = 0.01 \times 16 = 0.16 \text{ M}\]
Conclusion:
The maximum initial activity of the radioactive substance that can be injected to achieve an activity of 0.01 M after 24 hours is 0.16 M. so the correct Answer is Option (C)
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Concepts Used:

Chemical Kinetics

Chemical kinetics is the description of the rate of a chemical reaction. This is the rate at which the reactants are transformed into products. This may take place by abiotic or by biological systems, such as microbial metabolism.

Rate of a Chemical Reaction:

The speed of a reaction or the rate of a reaction can be defined as the change in concentration of a reactant or product in unit time. To be more specific, it can be expressed in terms of: (i) the rate of decrease in the concentration of any one of the reactants, or (ii) the rate of increase in concentration of any one of the products. Consider a hypothetical reaction, assuming that the volume of the system remains constant. R → P

Read More: Chemical Kinetics MCQ

Factors Affecting The Reaction Rate:

  • The concentration of Reactants - According to collision theory, which is discussed later, reactant molecules collide with each other to form products.
  • Nature of the Reactants - The reaction rate also depends on the types of substances that are reacting.
  • Physical State of Reactants - The physical state of a reactant whether it is solid, liquid, or gas can greatly affect the rate of change.
  • Surface Area of Reactants - When two or more reactants are in the same phase of fluid, their particles collide more often than when either or both are in the solid phase or when they are in a heterogeneous mixture. In a heterogeneous medium, the collision between the particles occurs at an interface between phases. Compared to the homogeneous case, the number of collisions between reactants per unit time is significantly reduced, and so is the reaction rate.
  • Temperature - If the temperature is increased, the number of collisions between reactant molecules per second. Increases, thereby increasing the rate of the reaction.
  • Effect Of Solvent - The nature of the solvent also depends on the reaction rate of the solute particles.
  • Catalyst - Catalysts alter the rate of the reaction by changing the reaction mechanism.