Given: - Work done by the gas during isobaric expansion: \(W = 200 \, \text{J}\) - For a diatomic gas, the ratio of specific heats \(\gamma = 1.4\).
Step 1: Relationship for an Isobaric Process
In an isobaric process, the heat supplied \(Q\) to the system is given by:
\[ Q = \Delta U + W \]
where \(\Delta U\) is the change in internal energy of the gas and \(W\) is the work done by the gas.
Step 2: Change in Internal Energy
The change in internal energy for a diatomic gas is given by:
\[ \Delta U = nC_V\Delta T \]
For a diatomic gas, the molar specific heat at constant volume \(C_V\) is:
\[ C_V = \frac{R}{\gamma - 1} = \frac{R}{1.4 - 1} = \frac{5R}{2} \]
The molar specific heat at constant pressure \(C_P\) is given by:
\[ C_P = C_V + R = \frac{5R}{2} + R = \frac{7R}{2} \]
Thus, for an isobaric process, the heat \(Q\) is given by:
\[ Q = nC_P\Delta T = \frac{7}{5}\Delta U \]
Using the relation between work and internal energy change for an isobaric process:
\[ W = \frac{2}{5}Q \]
Substituting the given value of \(W\):
\[ 200 = \frac{2}{5}Q \]
Solving for \(Q\):
\[ Q = \frac{5}{2} \times 200 = 500 \, \text{J} \]
Conclusion: The heat given to the gas during the process is \(700 \, \text{J}\).
For a given reaction \( R \rightarrow P \), \( t_{1/2} \) is related to \([A_0]\) as given in the table. Given: \( \log 2 = 0.30 \). Which of the following is true?
\([A]\) (mol/L) | \(t_{1/2}\) (min) |
---|---|
0.100 | 200 |
0.025 | 100 |
A. The order of the reaction is \( \frac{1}{2} \).
B. If \( [A_0] \) is 1 M, then \( t_{1/2} \) is \( 200/\sqrt{10} \) min.
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. \( t_{1/2} \) is 800 min for \( [A_0] = 1.6 \) M.
Match List - I with List - II:
List - I:
(A) Electric field inside (distance \( r > 0 \) from center) of a uniformly charged spherical shell with surface charge density \( \sigma \), and radius \( R \).
(B) Electric field at distance \( r > 0 \) from a uniformly charged infinite plane sheet with surface charge density \( \sigma \).
(C) Electric field outside (distance \( r > 0 \) from center) of a uniformly charged spherical shell with surface charge density \( \sigma \), and radius \( R \).
(D) Electric field between two oppositely charged infinite plane parallel sheets with uniform surface charge density \( \sigma \).
List - II:
(I) \( \frac{\sigma}{\epsilon_0} \)
(II) \( \frac{\sigma}{2\epsilon_0} \)
(III) 0
(IV) \( \frac{\sigma}{\epsilon_0 r^2} \) Choose the correct answer from the options given below:
Consider the following statements:
A. Surface tension arises due to extra energy of the molecules at the interior as compared to the molecules at the surface of a liquid.
B. As the temperature of liquid rises, the coefficient of viscosity increases.
C. As the temperature of gas increases, the coefficient of viscosity increases.
D. The onset of turbulence is determined by Reynolds number.
E. In a steady flow, two streamlines never intersect.
Choose the correct answer from the options given below: