A 25 mL sample of hard water is titrated with a 0.001 M solution of EDTA, and the end point of the titration is reached at 50 mL of EDTA added. What is the concentration of Ca$^{2+}$ and Mg$^{2+}$ ions in solution?
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When titrating water samples, the concentration of metal ions is related to the volume of EDTA used, based on the stoichiometry of the reaction.
Using the volume of EDTA required to reach the end point and the molarity of EDTA, the concentration of Ca$^{2+}$ and Mg$^{2+}$ ions in the sample is calculated to be 0.0005 M.