Let \(I\) =\(\int_{-5}^{5} |x+2|\,dx\)
It can be seen that (x+2)≤0 on [−5,−2] and (x+2)≥0 on [−2,5].
∴ \(I=\int^{-2}_{-5}-(x+2)dx+\int^5_{-2}(x+2)dx\) \(\bigg(\int^b_af(x)=\int^e_af(x)+\int^b_cf(x)\bigg)\)
I=\(-\bigg[\frac{x^2}{2}+2x\bigg]^{-2}_{-5}+\bigg[\frac{x^2}{2}+2x\bigg]^{5}_{-2}\)
=\(-\bigg[\frac{(-2)^2}{2}+2(-2)-\frac{(-5)^2}{2}-2(-5)\bigg]+-\bigg[\frac{(5)^2}{2}+2(5)-\frac{(-2)^2}{2}-2(-2)\bigg]\)
=-\(\bigg[\)2-4-\(\frac{25}{2}\)+10\(\bigg]\)+\(\bigg[\)\(\frac{25}{2}\)+10-2+4\(\bigg]\)
=-2+4+\(\frac{25}{2}\)-10+\(\frac{25}{2}\)+10-2+4
=29
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.