Question:

$3.6$ gram of oxygen is adsorbed on $1.2\, g$ of metal powder. What volume of oxygen adsorbed per gram of the adsorbent at $1\,atm$ and $273 \,K$ ?

Updated On: Mar 10, 2025
  • $0.19\, Lg ^{-1}$
  • $1\, Lg ^{-1}$
  • $2.1\, Lg ^{-1}$
  • None of these
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The Correct Option is C

Approach Solution - 1

Mass of oxygen adsorbed per gram of metal powder
$=\frac{3.6}{1.2} g =3\, g = m$ B
y ideal gas equation, $P V=n R T$
$\therefore V=\frac{ mRT }{ MP }=\frac{3 \times 273 \times 0.0821}{32 \times 1 atm }$
$=2.1\, Lg ^{-1}$
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Approach Solution -2

\(\text{Mass of }O_2​ \text{ per gram of adsorbent} =\frac{3.6​}{1.2}=3.0\)
\(\text{Number of moles of }O_2​ \text{ per gram of adsorbent} =\frac{3}{32}​\)
\(\text{Volume of }O_2​ \text{ per gram of adsorbent}=\frac{3}{32}​\times{\frac{0.0821\times273}{1}}​=2.10 L\)

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Approach Solution -3

\(\text{The correct option is C: 2.31 }Lg^{−1}\)
\(\text{Mass of }O_2\text{ adsorbed per gram of adsorbent} =\frac{3.6}{1.2}= 3\)
\(\text{Number of moles of }O_2\text{ per gram of adsorbent} = \frac{3}{32}\)
\(\text{Volume of }O_2\text{ per gram of adsorbent} =\frac{3}{32}\times\frac{(0.0821)\times(300)}{1}\)
=2.31 Lg−1
For the same approximation can be used i.e., R≈112\(R≈\frac{1}{12}\) L atm/mol K and you get the answer to be 2.34.

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Concepts Used:

Adsorption

Heinrich Kayser, the German physicist was the first to coin the term adsorption. Adsorption can be explained as a surface phenomenon where particles remain attached on the top of a material. Generally, it comprises the molecules, atoms, liquid, solid in a dissolved stage, even the ions of a gas that are attached to the surface. Much to our surprise, the consequence of surface energy i.e. adsorption is present in biological, physical, chemical, and natural systems and are used in many industrial applications.