Step 1: Using the centroid-orthocenter relation.
For a triangle, if \( A(x_1, y_1) \), \( B(x_2, y_2) \), and \( C(x_3, y_3) \) are its vertices, then the centroid \( G \) is given by:
\[
G = \left( \frac{x_1 + x_2 + x_3}{3}, \frac{y_1 + y_2 + y_3}{3} \right)
\]
We also know that the centroid \( G \) and orthocenter \( H \) are related by the property:
\[
H = 3G - 2O
\]
where \( O \) is the circumcenter.
Step 2: Compute the centroid of the triangle.
The given vertices are \( A(-2, -1) \), \( B(2,5) \), and \( C(m,n) \). The centroid \( G \) is:
\[
G = \left( \frac{-2 + 2 + m}{3}, \frac{-1 + 5 + n}{3} \right)
\]
Step 3: Solve for \( m \) and \( n \).
We are given that the orthocenter is \( H(2, 5/3) \). Using the centroid-orthocenter property:
\[
\left(2, \frac{5}{3} \right) = 3 \left( \frac{-2 + 2 + m}{3}, \frac{-1 + 5 + n}{3} \right) - 2G
\]
Simplifying:
\[
2 = \frac{-2 + 2 + m}{3}
\]
\[
\frac{5}{3} = \frac{-1 + 5 + n}{3}
\]
Solving for \( m \):
\[
2 \times 3 = -2 + 2 + m
\]
\[
m = 5
\]
Solving for \( n \):
\[
\frac{5}{3} \times 3 = -1 + 5 + n
\]
\[
5 = -1 + 5 + n
\]
\[
n = 1
\]
Step 4: Compute \( m+n \).
\[
m + n = 5 + 0 = 5
\]
Thus, the correct answer is:
\[
\boxed{5}
\]