Since the process is at constant volume, the change in internal energy \(\Delta U\) is given by:
\[\Delta U = ms\Delta T\]
where \(m = 0.08 \, \text{kg}\), \(s = 0.17 \, \text{kcal/kg}^\circ\text{C}\), and \(\Delta T = 5^\circ \text{C}\).
Convert \(s\) from kcal to joules:
\[s = 0.17 \times 1000 \times 4.18 \, \text{J/kg}^\circ\text{C}\]
Then,
\[\Delta U = 0.08 \times (0.17 \times 1000 \times 4.18) \times 5 \approx 284 \, \text{J}\]
For a given reaction \( R \rightarrow P \), \( t_{1/2} \) is related to \([A_0]\) as given in the table. Given: \( \log 2 = 0.30 \). Which of the following is true?
\([A]\) (mol/L) | \(t_{1/2}\) (min) |
---|---|
0.100 | 200 |
0.025 | 100 |
A. The order of the reaction is \( \frac{1}{2} \).
B. If \( [A_0] \) is 1 M, then \( t_{1/2} \) is \( 200/\sqrt{10} \) min.
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. \( t_{1/2} \) is 800 min for \( [A_0] = 1.6 \) M.
Let \( S = \left\{ m \in \mathbb{Z} : A^m + A^m = 3I - A^{-6} \right\} \), where
\[ A = \begin{bmatrix} 2 & -1 \\ 1 & 0 \end{bmatrix} \]Then \( n(S) \) is equal to ______.
The number of 6-letter words, with or without meaning, that can be formed using the letters of the word MATHS such that any letter that appears in the word must appear at least twice, is $ 4 \_\_\_\_\_$.
Let \( f : (0, \infty) \to \mathbb{R} \) be a twice differentiable function. If for some \( a \neq 0 \), } \[ \int_0^a f(x) \, dx = f(a), \quad f(1) = 1, \quad f(16) = \frac{1}{8}, \quad \text{then } 16 - f^{-1}\left( \frac{1}{16} \right) \text{ is equal to:}\]