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GATE CY
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Inorganic Chemistry
List of top Inorganic Chemistry Questions asked in GATE CY
The ground state of [Cr(H
2
O)
6
]
2+
is
GATE CY - 2024
GATE CY
Inorganic Chemistry
Coordination chemistry
The major product in the given reaction sequence is Q. The mass spectrum of Q shows
([M] = molecular ion peak)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Mass spectrometry
In aqueous solution of K
4
[Fe(CN)
6
], the allowed transition(s) is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Coordination chemistry
The complex(es) with distorted octahedral structure is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Coordination chemistry
1
H NMR spectrum of a mixture containing CH
3
Br (x mol) and (CH
3
)
3
CBr (y mol) shows two singlets at 2.7 ppm and 1.8 ppm, with the relative ratio of 3:1 (integration value), respectively. The value of x/y is ______.
(rounded off to the nearest integer)
GATE CY - 2024
GATE CY
Inorganic Chemistry
NMR and ESR spectroscopy
The order and the number of classes present in a group with the irreducible representations A
1
, A
2
, B
1
, B
2
, E
1
, and E
2
, are, respectively,
GATE CY - 2024
GATE CY
Inorganic Chemistry
Mass spectrometry
The reaction of XeF
2
with HN(SO
2
F)
2
at 273 K in CF
2
Cl
2
solvent yields
GATE CY - 2024
GATE CY
Inorganic Chemistry
Theories of bonding
Among the following, the NMR active nucleus (nuclei) is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
NMR and ESR spectroscopy
The heptacity of allyl and Cp and the ligation mode of NO in the thermodynamically stable complexes
[(η
x
-allyl)Ru(CO)
2
(NO)] and [(η
y
-Cp)Ru(CO)2(NO)],
respectively, are
(The heptacity of allyl and Cp are denoted by η
x
and η
y
, respectively.)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Coordination chemistry
Borax on treatment with NaOH and H
2
O
2
forms X. The compound X on reaction with PhCN at 60 °C in methanol-water mixture gives Y as the major product. X and Y, respectively, are
GATE CY - 2024
GATE CY
Inorganic Chemistry
Structure and Bonding of Boranes
The crystal field stabilization energy of [Cr(NH
3
)
6
]
3+
with Δ
0
value of 21600 cm
-1
is y cm
-1
. The value of |y| is_____.
(rounded off to the nearest integer)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Energy level diagrams in various crystal fields
The number of metal-metal bond(s) in the complex [(
5
η-Cp)Mo(CO)
2
]
2
is x and in [(
5
η-Cp)2Fe
2
(CO)
3
] is y. The value of x + y is ____.
(Assume 18 electron rule is followed.)
(Answer in integer)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Metal-carbonyl
The compound(s) which show(s) the perovskite structure in solid state is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Crystal systems and lattices
Among the following metalloproteins, the pair(s) of non-heme proteins is (are)
GATE CY - 2024
GATE CY
Inorganic Chemistry
Iron
Among the following, the compound with the lowest CO stretching frequency is
GATE CY - 2024
GATE CY
Inorganic Chemistry
Coordination chemistry
Which are optically active?
GATE CY
Inorganic Chemistry
Coordination chemistry