The e.m.f. of a Daniell cell at 298 K is E1. Zn/SO4 (0.01 M) || CuSO4 (1.0 M)/Cu. When the concentration of ZnSO4 is 1.0 M and that of CuSO4 is 0.01 M, the e.m.f. is changed to E2. What is the relationship between E1 and E2 ?