Question:

The number of atoms in $100\,g$ of an $fcc$ crystal with density, $d = {10\, g/cm^3}$ and cell edge equal to $100\,pm$, is equal to

Updated On: Jun 7, 2022
  • $2 \times 10^{25}$
  • $1 \times 10^{25}$
  • $4 \times 10^{25}$
  • $3 \times 10^{25}$
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The Correct Option is C

Solution and Explanation

${Mass} (m) = {100\, g; Density} (d) = 10\, {g/cm^3}$
and $ {length } \,(l) ={ 100\, pm = 100 \times 10^{-12}\, m }$
$= 100 \times 10^{-10}{ cm}$
We know that volume of the unit cell
$= (l)^3 ={ (100 \times 10^{-10} \, cm)^3 = 10^{-24}cm^3}$ and volume of 100 g of element
$= {\frac{Mass}{Density} = \frac{100}{10} = 10 \, cm^3}$
Therefore, number of unit cells = $\frac{10}{10^{-24}} = 10^{25}$
Since each fcc cube contains 4 atoms,
therefore total number of atoms in $100\, g$
$ = 4 \times 10^{25}$
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Concepts Used:

Unit Cells

The smallest portion of a crystal lattice which repeats in different directions to form the entire lattice is known as Unit cell.

The characteristics of a unit cell are:

  • The dimensions are measured along the three edges, a, b and c. These edges can form different angles, they may be mutually perpendicular or may not.
  • The angles held by the edges are α (between b and c) β (between a and c) and γ (between a and b).

Therefore, a unit cell is characterised by six parameters such as a, b, c and α, β, γ.

Types of Unit Cell:

Numerous unit cells together make a crystal lattice. Constituent particles like atoms, molecules are also present. Each lattice point is occupied by one such particle.

  1. Primitive Unit Cells: In a primitive unit cell constituent particles are present only on the corner positions of a unit cell.
  2. Centred Unit Cells: A centred unit cell contains one or more constituent particles which are present at positions besides the corners.
    1. Body-Centered Unit Cell: Such a unit cell contains one constituent particle (atom, molecule or ion) at its body-centre as well as its every corners.
    2. Face Centered Unit Cell: Such a unit cell contains one constituent particle present at the centre of each face, as well as its corners.
    3. End-Centred Unit Cells: In such a unit cell, one constituent particle is present at the centre of any two opposite faces, as well as its corners.