In a lead storage battery, the reactions at the anode, cathode, and overall reaction are as follows:
- Anode (oxidation):
\[
\text{Pb} + \text{SO}_4^{2-} \rightarrow \text{PbSO}_4 + 2e^-
\]
- Cathode (reduction):
\[
\text{PbO}_2 + \text{SO}_4^{2-} + 4H^+ + 2e^- \rightarrow \text{PbSO}_4 + 2H_2\text{O}
\]
- Overall reaction:
\[
\text{Pb} + \text{PbO}_2 + 2\text{H}_2\text{SO}_4 \rightarrow 2\text{PbSO}_4 + 2H_2\text{O}
\]
This is the reaction that takes place during the discharge of a lead storage battery.