Step 1: Use the cosine rule.
Using the cosine rule in triangle ABC:
\[
\cos C = \frac{a^2 + b^2 - c^2}{2ab}
\]
Given \( \angle C = 60^\circ \), we know that \( \cos 60^\circ = \frac{1}{2} \). Substituting the values of \( a \), \( b \), and \( C \), we can solve for the value of \( A - B \).
Step 2: Simplification.
After simplifying, we find that \( A - B = 90^\circ \). Therefore, the correct answer is \( 90^\circ \).
Step 3: Conclusion.
The correct answer is (D) 90°.