Read the following passage and answer the questions that follow.
The most convincing evidence to trace evolutionary relationships between humans and different groups of animals come from the basic similarities seen at the molecular level. Study the table given below that depicts the number of amino acid differences between the haemoglobin polypeptide of a few animals with that of humans and answer the questions that follow.
S.No. | Animal | No. of amino acid differences in haemoglobin with that of humans |
---|---|---|
1. | Macaque | 08 |
2. | Dog | 32 |
3. | Bird | 45 |
4. | Frog | 67 |
5. | Lamprey | 125 |
(a) To which category of evolution (Divergent or Convergent) do the following evolutionary relationships belong to:
(i) Humans and Macaque
(ii) Humans and Frog
(b) What do the biochemical similarities in haemoglobin suggest about the evolutionary relationship between humans, frog, and lamprey?
(c) (i) Which one of the two – lampreys’ or macaques’ evolution is more closely related to humans and why?
OR
(c) (ii) Which one of the two – frogs’ or dogs’ evolution is more closely related to humans and why?
(a) Calculate the standard Gibbs energy (\(\Delta G^\circ\)) of the following reaction at 25°C:
\(\text{Au(s) + Ca\(^{2+}\)(1M) $\rightarrow$ Au\(^{3+}\)(1M) + Ca(s)} \)
\(\text{E\(^\circ_{\text{Au}^{3+}/\text{Au}} = +1.5 V, E\)\(^\circ_{\text{Ca}^{2+}/\text{Ca}} = -2.87 V\)}\)
\(\text{1 F} = 96500 C mol^{-1}\)
Define the following:
(i) Cell potential
(ii) Fuel Cell
Calculate the emf of the following cell at 25°C:
\[ \text{Zn(s)} | \text{Zn}^{2+}(0.1M) || \text{Cd}^{2+}(0.01M) | \text{Cd(s)} \] Given: \[ E^\circ_{\text{Cd}^{2+}/\text{Cd}} = -0.40 \, V, \, E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, V \] \[ [\log 10 = 1] \]
Write chemical equations of the following reactions:
(i) Phenol is treated with conc. HNO\(_3\)
(ii) Propene is treated with B\(_2\)H\(_6\) followed by oxidation by H\(_2\)O\(_2\)/OH\(^-\)
(iii) Sodium t-butoxide is treated with CH\(_3\)Cl
Give a simple chemical test to distinguish between butan-1-ol and butan-2-ol.