Step 1: Understanding the Concept:
The question asks to identify a primary air pollutant from the given options.
Primary pollutants are substances directly emitted into the atmosphere from a source (e.g., from a factory chimney or a volcanic eruption).
Secondary pollutants are not directly emitted but form in the atmosphere when primary pollutants react with each other or with other atmospheric components.
Step 3: Detailed Explanation:
\[\begin{array}{rl} \bullet & \text{(A) Ash from a volcanic eruption: This is a primary pollutant. Volcanic ash is a particulate matter that is directly emitted from a natural source (the volcano) into the atmosphere.} \\ \bullet & \text{(B) Tropospheric Ozone (O\(_3\)): This is a classic example of a secondary pollutant. It is formed in the troposphere by the reaction of primary pollutants like nitrogen oxides (NOx) and volatile organic compounds (VOCs) in the presence of sunlight.} \\ \bullet & \text{(C) Stratospheric Ozone: This is not a pollutant. The ozone layer in the stratosphere is essential for life on Earth as it absorbs harmful ultraviolet (UV) radiation.} \\ \bullet & \text{(D) PAN (Peroxyacetyl nitrate): This is another common secondary pollutant, formed from the reaction of NOx and VOCs, and is a component of photochemical smog.} \\ \end{array}\]
Step 4: Final Answer:
Ash from a volcanic eruption is a primary air pollutant.