CO2
SO2
CH4
NOx
The phenomenon of "brown air" is primarily associated with the presence of nitrogen oxides, commonly represented as NOx. These compounds are significant air pollutants produced from combustion processes, such as those occurring in vehicles and industrial operations. NOx gases lead to the formation of photochemical smog, characterized by its brownish hue. This occurs when sunlight triggers a series of chemical reactions between NOx and other volatile organic compounds. The result is the generation of pollutants like ozone (O3) that contribute to smog's characteristic coloration.
Incorrect options:
Therefore, the correct answer is NOx, responsible for the formation of brown air due to its role in creating photochemical smog.