CO2
SO2
CH4
NOx
Brown air, also known as photochemical smog, is primarily caused by the presence of nitrogen oxides (NOx) in the atmosphere, along with volatile organic compounds (VOCs). When sunlight reacts with these pollutants, it leads to the formation of ground-level ozone and other secondary pollutants, which give the air a brownish appearance.
CO2 (Carbon dioxide) is a greenhouse gas that contributes to global warming but does not directly cause brown air.
SO2 (Sulfur dioxide) contributes to acid rain but is more associated with the formation of gray air rather than brown air.
CH4 (Methane) is a potent greenhouse gas and contributes to air pollution, but it is not directly responsible for brown air.
Thus, the presence of NOx in combination with VOCs is the main cause of brown air (photochemical smog).