Question:

Which of the following statements is not correct?

Updated On: Apr 20, 2025
  • Be and Mg give characteristic colour to the flame.
  • Be and Mg have high ionisation energy
  • Sulphates of Be and Mg are readily soluble in water.
  • All are correct
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The Correct Option is A

Solution and Explanation

The correct answer is:

Option 3: Sulphates of Be and Mg are readily soluble in water.

Explanation:

Option 1: Be and Mg give characteristic colour to the flame:

This statement is correct. Both beryllium (Be) and magnesium (Mg) salts give characteristic colours when burned in a flame. Beryllium gives a green flame, and magnesium produces a bright white flame.

Option 2: Be and Mg have high ionisation energy:

This statement is also correct. Beryllium and magnesium have relatively high ionisation energies due to their small atomic size and the strong attraction between the electrons and the nucleus.

Option 3: Sulphates of Be and Mg are readily soluble in water:

This statement is incorrect. While magnesium sulphate (MgSO₄) is soluble in water, beryllium sulphate (BeSO₄) is only sparingly soluble in water and requires high temperatures for dissolution.

Option 4: All are correct:

Since Option 3 is incorrect, this option is not valid.

Thus, Option 3 is the statement that is not correct.

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Concepts Used:

Group 1 Elements

Group one of alkali metals is s-block elements with just one electron in their s-orbital. They are are alkali metals. They are named so because of the alkaline nature of the hydroxides and oxides.

Alkali metals are characterized by one s-electron in the valence shell of their atoms.

Alkali metals have a corresponding [Noble gas] ns1 electronic configuration. They occupy the first column of the periodic table. Alkali elements are:

  • Lithium(Li)
  • Sodium(Na)
  • Potassium (K)
  • Rubidium (Ru)
  • Cesium (Cs)
  • Francium (Fr)

They have occupied successive periods from first to seven. Francium is a radioactive element with very low half-life.

Electronic Configuration:

  • Alkali metals have one electron in their valence shell.
  • The electronic configuration is given by ns1. For example, the electronic configuration of lithium is given by 1ns1 2ns1.
  • They tend to lose the outer shell electron to form cations with charge +1 (monovalent ions).

This makes them the most electropositive elements and due to the same reason, they are not found in the pure state.