Question:

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R:
Assertion A: Metallic sodium dissolved in liquid ammonia giving a deep blue solution which is paramagnetic.
Reasons R: The deep blue solution to the formation of amide.
In the light of the above statements, the correct answer from the options below:

Updated On: May 1, 2025
  • Both A and R are true but R is the correct explanation of A.
  • A is true but R is false.
  • A is false but R is true.
  • Both A and R are true and R is the correct explanation of A.
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The Correct Option is B

Solution and Explanation

To solve this problem, we need to evaluate both the assertion and the reason:
Assertion A: Metallic sodium dissolved in liquid ammonia gives a deep blue solution which is paramagnetic.
This statement is true. When metallic sodium is dissolved in liquid ammonia, it forms solvated electrons which impart a deep blue color to the solution. These solvated electrons are unpaired and therefore the solution is paramagnetic.
Reason R: The deep blue solution is due to the formation of amide.
This statement is false. The deep blue color is not due to the formation of amide. The color and paramagnetism are due to the presence of solvated (unpaired) electrons, not amide ions.
Therefore, based on the analysis above, the correct conclusion is:
A is true but R is false.
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Concepts Used:

S-Block Elements

S-block elements, also known as alkali and alkaline earth metals, constitute the first two groups of the periodic table.

Group 1 elements, including hydrogen, lithium, sodium, potassium, rubidium, cesium, and francium, are alkali metals characterized by low density, high reactivity, and the ability to form strong bases when combined with water. They showcase a single valence electron in their outermost shell, making them eager to lose it in chemical reactions.

Group 2 elements, beryllium, magnesium, calcium, strontium, barium, and radium, make up the alkaline earth metals in Group 2. These metals share similar properties, such as higher densities and melting points compared to alkali metals. They also have a tendency to form ionic compounds with nonmetals.

S-block elements play vital roles in various industrial and biological processes. Alkali metals find applications in batteries, while alkaline earth metals are crucial for construction materials and are essential nutrients for living organisms. Despite their importance, the reactivity of alkali metals requires careful handling, often stored in oil to prevent reactions with moisture or oxygen. Overall, s-block elements contribute significantly to the diverse applications of chemistry in our daily lives.