The polarity of a bond depends on the difference in electronegativity between the two atoms involved. The greater the difference in electronegativity, the more polar the bond will be.
- In \( {HF} \), fluorine is highly electronegative compared to hydrogen, creating a large difference in electronegativity and resulting in the most polar bond among the options.
Thus, the molecule with the most polar bond is \( \boxed{{HF}} \).