Question:

Which of the following is the slope of the first order reaction in the plot of ln[R] vs. time ?

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First order: slope of ln[R] vs. t is always negative.
  • +k
  • $\frac{+k}{2.303}$
  • –k
  • $\frac{–k}{2.303}$
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The Correct Option is C

Solution and Explanation

For a first order reaction, the integrated rate law is:
ln[R] = –kt + ln[R]$_0$
So, the slope when plotting ln[R] vs. time is –k.
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