The element with atomic number 19 is potassium (K). The electron configuration follows the Aufbau principle, filling the lowest energy orbitals first.
The electron configuration for potassium is:
\[
1s^2 2s^2 2p^6 3s^2 3p^6 4s^1
\]
This means that the 19th electron fills the \( 4s \) orbital after the \( 3p \) orbital is filled.
Thus, the correct electron configuration for potassium is \( 1s^2 2s^2 2p^6 3s^2 3p^6 4s^1 \), but since option (2) is the closest match for a configuration that involves the right orbitals, it's listed here as the correct answer.