Which of the following is not correctly matched?
Which of the following is not correctly matched?
- $PCl_5$ - $sp^3d$ hybridisation
- $PCl_3$ - $sp^3$ hybridisation
- $PCl_{5}$ (solid) - $\left[PtCl_{4}\right]^{+} \left[PtCl_{6}\right]^{-}$
- $PCl_5$ - brownish powder
The Correct Option is C
Solution and Explanation
\(PCl_5\) is yellowish-white powder.
PCl5 is used as a chlorinating reagent. It is a colorless, water-sensitive, and moisture-sensitive solid. In the solid state, PCl5 exists as an ionic solid, [PCl4]+[PCl6]−. The cation, [PCl4]+ is tetrahedral and sp3 hybridized. The anion, [PCl6]− is octahedral and is sp3d2 hybridized.
Top Questions on p -Block Elements
- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below:- JEE Main - 2024
- Chemistry
- p -Block Elements
- Identify the correct statements about p-block elements and their compounds.
(A) Non metals have higher electronegativity than metals.
(B) Non metals have lower ionisation enthalpy than metals.
(C) Compounds formed between highly reactive nonmetals and highly reactive metals are generally ionic.
(D) The non-metal oxides are generally basic in nature.
(E) The metal oxides are generally acidic or neutral in nature.- JEE Main - 2024
- Chemistry
- p -Block Elements
- $\textbf{Reduction potential of ions are given below:}$
\[ \begin{array}{ccc} \text{ClO}_4^- & \text{IO}_4^- & \text{BrO}_4^- \\ E^\circ = 1.19 \, \text{V} & E^\circ = 1.65 \, \text{V} & E^\circ = 1.74 \, \text{V} \\ \end{array} \]
The correct order of their oxidising power is:- JEE Main - 2024
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- p -Block Elements
The number of oxygen atoms present in chemical formula of fuming sulphuric acid is _______.
- JEE Main - 2024
- Chemistry
- p -Block Elements
- Taking stability as the factor, which one of the following represents correct relationship?
- NEET (UG) - 2023
- Chemistry
- p -Block Elements
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- Transcription
Concepts Used:
P-Block Elements
- P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
- P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.
P block elements consist of:
- Group 13 Elements: Boron family
- Group 14 Elements: Carbon family
- Group 15 Elements: Nitrogen family
- Group 16 Elements: Oxygen family
- Group 17 Elements: Fluorine family
- Group 18 Elements: Neon family