Question:

Given below are two statements: 
Statement I: Nitrogen forms oxides with +1 to +5 oxidation states due to the formation of $\mathrm{p} \pi-\mathrm{p} \pi$ bond with oxygen.
Statement II: Nitrogen does not form halides with +5 oxidation state due to the absence of d-orbital in it. 
In the light of the above statements, choose the correct answer from the options given below:

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Nitrogen's ability to form oxides and halides depends on its electronic configuration and the availability of d-orbitals.
Updated On: Apr 25, 2025
  • Statement I is true but Statement II is false
  • Both Statement I and Statement II are false
  • Statement I is false but Statement II is true
  • Both Statement I and Statement II are true
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The Correct Option is D

Solution and Explanation

1. Statement I: - Nitrogen can form oxides with oxidation states from +1 to +5 due to the formation of $\mathrm{p} \pi-\mathrm{p} \pi$ bonds with oxygen. - This statement is true. 
2. Statement II: - Nitrogen does not form halides with a +5 oxidation state due to the absence of d-orbitals. 
- This statement is true. Therefore, the correct answer is (4) Both Statement I and Statement II are true.

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