Question:

Which of the following is/are the CORRECT option(s) for the Joule-Thomson effect?

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The Joule-Thomson effect for real gases depends on temperature and pressure. At low temperatures, most gases cool upon expansion, while at high temperatures, they may heat up.
Updated On: Aug 30, 2025
  • It is an isentropic process
  • It is an isenthalpic process
  • It can result in cooling as well as heating
  • For an ideal gas it always results in cooling
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The Correct Option is B

Solution and Explanation

- The Joule-Thomson effect refers to the temperature change in a real gas when it is allowed to expand freely at constant enthalpy.
- (A) It is an isentropic process: This is incorrect. The Joule-Thomson effect occurs at constant enthalpy, not entropy, so it is not isentropic.
- (B) It is an isenthalpic process: This is correct. In a Joule-Thomson expansion, the enthalpy remains constant.
- (C) It can result in cooling as well as heating: This is correct. For most gases, the Joule-Thomson effect results in cooling, but for some gases (e.g., hydrogen, helium) it results in heating under certain conditions.
- (D) For an ideal gas it always results in cooling: This is incorrect. An ideal gas does not experience a Joule-Thomson effect because its internal energy depends only on temperature, not volume, so no cooling or heating occurs during expansion.
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