Step 1: Understanding primary and secondary refrigerants.
- Primary refrigerants change phase to absorb heat and are directly responsible for cooling (e.g., NH$_3$, CO$_2$, R$_{12}$).
- Secondary refrigerants are used to transfer the heat absorbed by primary refrigerants without undergoing phase change themselves.
Step 2: Explanation of incorrect options.
- (A) NH$_3$ (Ammonia): A primary refrigerant used in refrigeration systems.
- (C) CO$_2$ (Carbon dioxide): Another primary refrigerant commonly used in refrigeration systems.
- (D) R$_{12}$ (Dichlorodifluoromethane): A now-outdated primary refrigerant, formerly used in refrigeration systems.
Step 3: Selecting the correct option.
Since H$_2$O (water) is commonly used as a secondary refrigerant in systems such as chilled water systems, the correct answer is (B) H$_2$O.