Question:

Which of the following contains the maximum number of lone pairs on the central atom?

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To find the number of lone pairs on the central atom, calculate the total valence electrons, subtract bonding electrons, and divide the remainder by 2.
Updated On: Apr 3, 2025
  • ClO3
  • XeF4
  • SF4
  • I3
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The Correct Option is D

Approach Solution - 1

  • ClO3: Central Cl atom has 1 lone pair.
  • XeF4: Central Xe atom has 2 lone pairs.
  • SF4: Central S atom has 1 lone pair.
  • I3: Central I atom has 3 lone pairs.

Thus, I3 has the maximum number of lone pairs (3) on its central atom.

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Approach Solution -2

Correct Answer:

Option 4: I3-

Explanation:

  • ClO3-: 1 lone pair on Cl.
  • XeF4: 2 lone pairs on Xe.
  • SF4: 1 lone pair on S.
  • I3-: 3 lone pairs on the central I.

I3- has the maximum number of lone pairs (3) on the central iodine atom.

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