Question:

Which of the following compounds is known as inorganic benzene?

Updated On: Apr 7, 2025
  •  B6H6

  •  C5H5B

  •  C3N3H3

  •  B3N3H6

  •  BF3

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The Correct Option is D

Approach Solution - 1

Inorganic benzene identification:

  • B3N3H6 (Borazine):
    • Cyclic structure alternating B and N atoms
    • Isoelectronic/isostructural with benzene
    • Called "inorganic benzene"
  • Other options are either incorrect or not analogous to benzene

Thus, the correct option is (D): B3N3H6.

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Approach Solution -2

1. Understanding the question:

The compound referred to as "inorganic benzene" is a cyclic molecule that resembles benzene (\(C_6H_6\)) in structure but is composed of inorganic elements. It has alternating single and double bonds in a six-membered ring, similar to the aromatic structure of benzene.

2. Analyze each option:

  • (A) \(B_6H_6\):
    • This compound does not have a structure resembling benzene. It is not planar and lacks alternating single and double bonds. It is not known as inorganic benzene.
  • (B) \(C_5H_5B\):
    • This compound contains carbon and boron, but it does not form a six-membered ring. It is unrelated to inorganic benzene.
  • (C) \(C_3N_3H_3\):
    • This compound contains carbon and nitrogen, but it forms a three-membered ring rather than a six-membered ring. It is not inorganic benzene.
  • (D) \(B_3N_3H_6\):
    • This compound, also called borazine, has a six-membered ring with alternating boron and nitrogen atoms. It exhibits resonance and structural similarity to benzene, earning it the nickname "inorganic benzene." This is the correct answer.
  • (E) \(BF_3\):
    • This is a trigonal planar molecule and does not form a cyclic structure. It is unrelated to inorganic benzene.

3. Final answer:

The compound known as inorganic benzene is \(B_3N_3H_6\), which corresponds to Option (D).

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Top Questions on Structural Representations Of Organic Compounds

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Concepts Used:

Structure of Organic Compounds

The three structural formulas – complete structure, condensed structure, and bond line structural formulas are explained below:

Complete Structural Formula-

The Lewis dot structure is considered as the complete structural formula. In Lewis structure, the covalent bonds in the compound are denoted by a dash (―). This helps to emphasize the number of bonds formed by the electrons. Every single bond, a double bond, and a triple bond are represented by one dash, double dash, and triple dash respectively. It illustrates every single bond formed between every atom in the compound, thus called complete structural formula.

Condensed Structural Formula-

Since complete structural formula consumes much time and space to represent the structure, we can condense them. This is the condensed structural formula, where replacing some dashes/bonds by a number of identical groups attached to an atom by a subscript.

Bond Line Structural Formula-

A bond lines structural formula is another way of structural representation of organic compounds.  Here, every bond is represented as a line in a zigzag manner. If not specified, every terminal is assumed to be a methyl (-CH3) group.