Identify Z in the following reaction sequence.
Step 1: Trace the reaction steps. The sequence involves the conversion of an amide to a carboxylic acid group, likely involving steps that introduce or modify amine functionalities.
Step 2: Analyze the plausible structure of Z. Given the reaction sequence and typical outcomes, the formation of a carboxamide (CONH2) from the described reagents and conditions is most consistent with the chemistry involved.
To solve the problem, we need to identify the compound \( Z \) in the given reaction sequence. The sequence is as follows:
1. Step 1:
The first step involves the reaction of methyl chloride (CH₃COCl) with aluminum chloride (AlCl₃), which is a Friedel-Crafts alkylation reaction. This step introduces a methyl group to the benzene ring, resulting in methylbenzene (toluene).
2. Step 2:
In the second step, the methyl group on toluene undergoes oxidation with potassium permanganate (KMnO₄) in an alkaline medium, which oxidizes the methyl group to a carboxylic acid group (-COOH). This results in benzoic acid (C₆H₅COOH).
3. Step 3:
In the third step, benzoic acid undergoes reduction with ammonia (NH₃), which leads to the formation of an amine group (-NH₂) replacing the carboxyl group. This results in aniline (C₆H₅NH₂).
4. Conclusion:
The compound \( Z \) formed after these reactions is aniline (C₆H₅NH₂), which is option (3).
Final Answer:
The correct option is (C) aniline (C₆H₅NH₂).
List-I | List-II | ||
(A) | NH3 | (I) | Trigonal Pyramidal |
(B) | BrF5 | (II) | Square Planar |
(C) | XeF4 | (III) | Octahedral |
(D) | SF6 | (IV) | Square Pyramidal |
(1) \( x_1 = y_1 \)
(2) \( \frac{x_1 + x_2}{2} = \frac{y_1 + y_2}{2} \)
(3) \( x_2 = y_2 \)
(4) \( (x_1 - x_2)^2 = (y_1 - y_2)^2 \)
What is Y in the following reaction sequence?
Arrange the following in the increasing order of number of unpaired electrons present in the central metal ion:
I. \([MnCl_6]^{4-}\)
II. \([FeF_6]^{3-}\)
III. \([Mn(CN)_6]^{3-}\)
IV. \([Fe(CN)_6]^{3-}\)