Step 1: Understanding the toxicity of substances.
- Phosgene is highly toxic and was used as a chemical weapon.
- Gaseous chlorine is toxic and can cause severe damage to the respiratory system.
- Phosphine is highly toxic and can be lethal in even small amounts.
- Red phosphorus is relatively less toxic and is used safely in matches and other applications.
Step 2: Conclusion.
The correct answer is (D) Red phosphorus, as it is non-poisonous compared to the other options.