Step 1: Understand Brewster's Law.
When light undergoes complete polarization upon reflection, the angle between the reflected and refracted rays is 90°. This condition occurs at the Brewster angle \( \theta_B \), which is the angle of incidence at which the reflected light is completely polarized.
Step 2: Brewster's Angle Condition.
At the Brewster angle, the angle between the reflected and refracted rays is always 90° because the reflected and refracted rays are perpendicular to each other.
Final Answer: The correct angle between the reflected and refracted rays is \( \boxed{90^\circ} \).