Step 1: {Understanding Brewster's Law}
According to Brewster's law, when light is incident at the Brewster angle, the reflected light is completely polarized.
At this angle, the reflected and refracted rays are perpendicular to each other.
Step 2: {Derivation of the Perpendicular Relation}
\[ \theta_{{reflected}} + \theta_{{refracted}} = 90^\circ \] Thus, the angle between the reflected and refracted rays is: \[ \theta = 90^\circ \] Thus, the correct answer is \( 90^\circ \).