Question:

What is ‘X’ in the following reaction?
2–Bromo–2–methyl butane $\xrightarrow{X}$ 2–methyl–2–butanol

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Tertiary alkyl halides react with water via SN1 mechanism to form tertiary alcohols.
Updated On: May 19, 2025
  • CH$_2$Cl$_2$
  • CH$_3$CN
  • (CH$_3$)$_2$N–CHO
  • H$_2$O
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The Correct Option is D

Approach Solution - 1

2–Bromo–2–methylbutane is a tertiary alkyl halide. When it is treated with water (H$_2$O), it undergoes nucleophilic substitution (SN1 mechanism) to form the corresponding alcohol — 2–methyl–2–butanol. Water acts as the nucleophile and replaces the bromine atom with a hydroxyl group (–OH).
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Approach Solution -2

What is ‘X’ in the following reaction?

2–Bromo–2–methylbutane → X → 2–methyl–2–butanol

Step 1: Analyze the reaction type:
The reaction involves conversion of an alkyl halide (2–Bromo–2–methylbutane) to an alcohol (2–methyl–2–butanol).
This is a typical nucleophilic substitution reaction (SN1 type) where the halide (Br⁻) is replaced by a hydroxyl group (OH⁻).

Step 2: Suitable reagent for substitution:
Since the compound is tertiary (due to the 2-methyl-2-butyl structure), SN1 mechanism is favored.
Thus, the reaction proceeds with water (H₂O) as the nucleophile under mild conditions.

Therefore, the correct reagent X is:
\[ \boxed{\textbf{H}_2\textbf{O}} \]
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